What are PFAS? Types, applications, restrictions, etc.

“PFAS”(per- and polyfluoroalkyl substances) are defined as a group of chemical substances with a specific chemical structure that contain at least one fully fluorinated carbon atoms.
Only four groups of substances, i.e., PFOS, PFOA, PFHxS and LC PFCAs (Long Chain Perfluorocarboxylic Acids, C9-C21), their salts and related compounds are currently prohibited due to concerns about their impact on the environment and human health under the Stockholm Convention on Persistent Organic Pollutants (the “POPs Convention”).
Other PFAS that are not restricted are used in many different applications in everyday life and industry.
They contribute greatly to sustainable development, and technological and scientific advances.
This page features a variety of information about PFAS, including basic facts about PFAS, their types and applications, and regulations in Japan.

01 Basic facts about PFAS

What are PFAS?

“PFAS” (per- and polyfluoroalkyl substances) are a group of chemical substances with a specific chemical structure that contain fluorine atoms. PFAS have many specific characteristics which in combination cannot be effectively replicated by other materials. These characteristics include heat resistance, fire resistance and electrical insulation, which makes them critical in the various aspects of daily life to improve society and support a sustainable, carbon neutral world.

Types of PFAS

There is an extremely large variety of types of PFAS, each with its own different properties1. According to the United States Environmental Protection Agency (EPA), there are said to be approximately 12,000 types of PFAS2. Among the chemical substances classified as only PFAS, PFOS, PFOA, PFHxS and LC-PFCAs (C9-C21 PFCAs), their salts and related compounds are listed under the POPs Convention, because they have been found to be persistent in the environment or bio-accumulative and may have potential adverse health effects.

Four groups of substances of PFAS were listed for restriction under the POPs Convention

02 Applications of PFAS

PFAS, excluding these four groups of substances of PFAS, are used in various applications in daily life and industry. PFAS have various combinations of properties, such as being highly resistant to heat, chemicals, and ultraviolet rays, highly repellant to fluids, such as water and oil, less adhesive, less conductive to electricity, and less refractive to light. Due to these properties, PFAS are used in a variety of existing and future technologies that contribute greatly to sustainable development, a net-zero carbon society, and technological and scientific advances. These include energy, renewables, semiconductors, and telecommunications. For example, PFAS are used as indispensable substances in photoresists applied to semiconductors to print circuits onto the base material, and as a separator material (separating positive and negative electrodes) in lithium-ion batteries.

Fluorine products
used in daily life

Fluorine products have multiple
advanced functions
that are critical
to various aspects of daily life.

functions of fluorine products and examples of their applications

Going forward, there are further expectations for the use of PFAS, such as a material used in the electrodes of fuel cells, which will be needed to realize a hydrogen society, and as a material used in electrolytes to extract hydrogen from water. PFAS are also expected to be used in electronic substrates and cables in equipment for high-speed communication, such as 5G and 6G.

Growing expectations
for PFAS
in industries
for the next generation

Energy sector
Transportation sector
Electronics / Electric appliances / Telecommunication sectors

PFAS are indispensable materials for the future realization of a carbon-free society and digital society.

03 PFAS FAQ

Q1.
Do PFAS have any impact
on the environment and human health?

PFAS is a very large group of chemicals and not all PFAS have the same properties and impacts. Fluoropolymers, a subclass of PFAS, are chemically inert, non-bioavailable, and environmentally stable, distinguishing them from other PFAS substances. 96% of fluoropolymers display properties predictive of low hazard, which has been demonstrated by data in regulatory submissions and peer-reviewed literature3 4. While the OECD has not officially established a “Polymer of Low Concern” classification, the industry has assessed fluoropolymers and data demonstrate their low hazard when compared against criteria used by a range of global regulatory scientists to assess the safety of polymers. Such criteria are a compilation of intrinsic physical and chemical properties that anticipate potential health and environmental impact.

Q2.
Are there any restrictions or rules concerning PFAS?

Among the chemicals substances classified as PFAS, PFOS, PFOA, PFHxS are already regulated under the POPs Convention and the “Act on the Regulation of Manufacture and Evaluation of Chemical Substances” (CSCL) in Japan. Furthermore, LC-PFCAs (C9-C21 PFCAs) have been regulated under the POPs Convention and will also be regulated under the CSCL.

History of PFAS Regulation

Q3.
What is AGC’s response
to the restricted PFAS to date?

Among the four restricted PFAS, the AGC Group has never manufactured PFOS and PFHxS, and it discontinued the use, manufacture, and sale of PFOA and LC-PFCAs prior to their listing under the Stockholm Convention and CSCL. To fulfill our corporate responsibility to society, the AGC Group is committed to proactive efforts to minimize the environmental footprint of its business activities and to reduce the environmental impact of its products, based on scientific evidence5. The AGC Group will continue to provide fluorine products that are indispensable for customers and society in a responsible manner, in our efforts to support the daily lives of people around the world.

TOPICS

  • Feb 16, 2024
    Publication of this webpage
  1. 1The PFAS that are being studied most include PFOA, PFNA, PFHpA, PFBA, PFPeA, PFHxA, PFDA, PFUnA, PFDoA, PFTrDA, PFTeDA, PFOS, PFBS, PFDS, PFNS, PDHpS, PFPeS, 6:2FTOH, and 8:2FTOH. (See: Ministry of Environment, Reference Material 1: “Overview of PFAS” (Japanese only), 1st Comprehensive Strategy Review Expert Meeting for PFAS, January 30, 2023; United States Interstate Technology & Regulatory Council (ITRC), “PFAS — Per- and Polyfluoroalkyl Substances”)
  2. 2See “PFAS Master List of PFAS Substances,” United States Environmental Protection Agency. This is a comprehensive list of PFAS in which researchers and regulatory authorities around the world are interested. It currently lists 12,034 substances (last update: August 10, 2021)
  3. 3Henry B. J., Carlin P. J., Hammerschmidt J. A., Buck, R. C., Buxton W., Fiedler H., Seed J., Hernandez O. (2018). A Critical Review of the Application of Polymer of Low Concern and Regulatory Criteria to Fluoropolymers, Integr Environ Assess Manag2018:316–334
    https://setac.onlinelibrary.wiley.com/doi/epdf/10.1002/ieam.4035
  4. 4Korzeniowski S.H., Buck, R. C., Newkold R. M., El kassmi A., Laganis E., Matsuoka Y., Dinelli B., Beauchet S., Adamsky F., Weilandt K. ,Soni V., Kapoor D., Gunasekar P., Malvasi M., Brinati G., Musio S. (2022). A critical review of the application of polymer of low concern regulatory criteria to fluoropolymers II: Fluoroplastics and fluoroelastomers, Integr Environ Assess Manag2022:1-30
    https://setac.onlinelibrary.wiley.com/doi/epdf/10.1002/ieam.4646
  5. Please refer to 5Environmental Initiatives of the AGC Group (Japanese only)